Been confirmed the Blu-Ray with episode 6 and 7 is coming out on the 26th of June. Still haven't been able to find any uploads or image comparisons between the blu-ray and TV airing. Though I feel it's gonna be hard to see given you'd need a region free blu-ray player for them to work
https://en.anmosugoi.com/the-100-gir...-in-blu-ray-4/