We've got a game changer here.
The newest episode of Amazing Ladybug has goth girl Juleka transformed into the villain "Reflekta", and we get some super kinky twinny shenanigans.
Quote:
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Originally Posted by From the Ladybug wiki
Synopsis
Absent from the class photo because of Chloé, Juleka is akumatized. Becoming Reflekta, she transforms everyone into her own image, even Cat Noir! Only one superhero remains to stop her: Ladybug![2]
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There's no mental changes, but she goes on fairly fun romp clonifying herself across her school and town, even making the heroines sidekick/love interest (Cat Noir) into her clone. Her appearance and outfit is just stunning, ultimately the ep takes twinning as a kink to its purest.